Iodine pentafluoride is an interhalogen compound with chemical formula IF5. It is one of the fluorides of iodine. It is a colorless liquid, although impure samples appear yellow. It is used as a fluorination reagent and even a solvent in specialized syntheses.
Preparation It was first synthesized by Henri Moissan in 1891 by burning solid iodine in fluorine gas. This exothermic reaction is still used to produce iodine pentafluoride, although the reaction conditions have been improved.
I2 + 5 F2 → 2 IF5
Reactions IF5 reacts vigorously with water forming hydrofluoric acid and iodic acid: IF5 + 3 H2O → HIO3 + 5 HF Upon treatment with fluorine, it converts to iodine heptafluoride: IF5 + F2 → IF7
It has been used as a solvent for handling metal fluorides. For example, the reduction of osmium hexafluoride to osmium pentafluoride with iodine is conducted in a solution in iodine pentafluoride: 10 OsF6 + I2 → 10 OsF5 + 2 IF5
Primary amines react with iodine pentafluoride forming nitriles after hydrolysis.
References
Further reading
External links WebBook page for IF5 National Pollutant Inventory - fluoride and compounds fact sheet web elements listing