Iodide hydrides are mixed anion compounds containing hydride and iodide anions. Many iodide hydrides are cluster compounds, containing a hydrogen atom in a core, surrounded by a layer of metal atoms, encased in a shell of iodide.
List
formulasystemspace groupunit cell Åvolumedensitycommentreference(DippNacnac)Mg(μ-H)(μ-I)Mg(MesNacnac)KHI[LZnI(η2-H)]2 (L=1,3-bis(2,6-diisopropylphenyl)inidazole-2-ylidineSr2H3ItrigonalPm1a = 4.260 c = 7.749 Z=1121.774.16transparentYIHC=31.033metallicYIH2P3m1a = 3.8579, c = 10.997light greenNb6I11HD10/2ha = 11.317; b = 15.471 ; c = 13.431Nb6I11HImma = 11.317; b = 15.471 ; c = 13.431blackNb6(H)I9StriclinicP1a = 10.340, b = 11.554, c = 10.181, α = 104.31°, β = 113.50°, γ = 105.48° Z=2HCsNb6I11Ba2H3ItrigonalPm1a= 4.519 c= 8.1184transparentBa5H2I4O2orthorhombicCmcma =17.210, b = 14.525 c = 6.3903 Z=41597.445.11transparentLaI2HhexagonalP63/mmca=4.2158 c=15.508Cel2H0.90R3mCel2D0.96R3mNdI2HGdI2H0.97R3mtransparent blueGd2ICH0.73P63mca=3.8128 C=14.844 Z=28.071Eu2H3Idark redEu5H2O2I4orthorhombicCmcma = 16.3697, b = 13.6954, c = 6.0436, Z = 4dark redTb2ICHDyI2H[(η5-C5H5)W(NO)IH]2(η5-C5H5)W(NO)I(H)(P(OPh)3)Ir(η2-H2)(H)2I(PiPr3)2Ir(η2-H2)(H)2I(PiPr3)2•C10H8triclinicPa=7.999 b=13.981 c=14.561 α=82.49° β=84.39° γ=71.70° Z=215K
References