Terphenylquinones are fungal dyes from the group of phenyl-substituted p-benzoquinones having the following general structure.
General chemical structure of terphenylquinones Also derivatives with a central o-benzoquinone structure are known.
Biosynthesis The biosynthesis of terphenylquinones is carried out by dimerization of substituted oxophenylpropanoic acids (phenylpyruvic acids).
Occurrence Terphenylquinones are typical constituents of the Boletales.
Examples {|class="wikitable sortable" !Name||Structure|| CAS-Nr.||Origin |- |Polyporic acid||||548-59-4||Polypore of the order Aphyllophorales, lichen Yarrumia coronata |- |Atromentin||||519-67-5||Paxillus atrotomentosus (Basidiomycota) |- |Aurantiacin||||548-32-3||Hydnellum aurantiacum (Basidiomycota) |- |Phlebiarubron||||7204-23-1|| Cultures of Phlebia strigosozonata and Punctularia atropurpurascens (Basidiomycota) |- |Spiromentin B||||121254-56-6||Tapinella atrotomentosa (Basidiomycota) and cultures of Tapinella panuoides
See also
Thelephoric acid
References