Mulville is a surname. Notable people with the surname include:
Daniel Mulville (born 1939), American engineer who served briefly as Acting Administrator of NASA in 2001 Jacqui Mulville (active from 1995), British bioarchaeologist Jimmy Mulville (born 1955), English comedian, comedy writer, producer and television presenter
See also Melville (disambiguation) Mulville House, a historic house in Norfolk, Connecticut