Alicea is a surname. Notable people with the surname include:
Carolette Alicea, American politician Francisco Parés Alicea, Puerto Rican accountant and government official Geraldo Alicea (born 1963), American politician Ismael Alicea (1954–2015), American librarian Jose Alicea Mirabal (born 1967), Puerto Rican basketball player Luis Alicea (born 1965), Puerto Rican baseball player William Alicea Pérez, Puerto Rican politician
Fictional characters Vitin Alicea, a Puerto Rican television and radio character