Carbokentbrooksite is a very rare mineral of the eudialyte group,Mindat, Carbokentbrooksite, http://www.mindat.org/min-25674.html with formula (Na,□)12(Na,Ce)3Ca6Mn3Zr3NbSiO(Si9O27)2(Si3O9)2(OH)3(CO3).H2O.Khomyakov, A.P., Dusmatov, V.D., Ferraris, G., Gula, A., Ivaldi, G., and Nechelyustov, G.N., 2003: Zirsilite-(Ce), (Na,[])12(Ce,Na)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)•H2O, and carbokentbrooksite (Na,[])12(Na,Ce)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)•H2O – two new eudialyte-group minerals from the Dara-i-Pioz alkaline massif, Tajikistan. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva 132(5), 40–51 (in Russian, with English abstract); in: Jambor, J.I, and Roberts, A.C., 2004: New mineral names. American Mineralogist 89(11–12), 1826–1834 The original formula was extended to show the presence of cyclic silicate groups and silicon at the M4 site, according to the nomenclature of eudialyte group.Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785–794 Carbokenbrooksite characterizes in being carbonate-rich (the other eudialyte-group species with essential carbonate are zirsilite-(Ce), golyshevite, and mogovidite). It is also sodium rich, being sodium equivalent of zirsilite-(Ce), with which it is intimately associated.
Occurrence and association Carbokentbrooksite and zirsilite-(Ce) are found as replacements of grains and crystals of eudialyte. They occur in pegmatites of Darai-Pioz alkaline massif, Tajikistan – a locality known for many rare minerals. The minerals are associated with aegirine, ekanite, microcline, polylithionite, quartz, stillwellite-(Ce) (silicates), pyrochlore-group mineral, fluorite, calcite, and galena.
Notes on chemistry Beside the elements given in the formula, carbokentbrooksite contains admixtures of lanthanum, strontium, neodymium, iron, yttrium, titanium, potassium, chlorine, and praseodymium. Carbokentbrooksite and zirsilite-(Ce) are chemically similar.
Notes on structure Carbokentbrooksite is isostructural with kentbrooksite.
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