Paiement is a surname. Notable people with the surname include:
Alain Paiement (born 1960), Canadian artist André Paiement (1950–1978), Canadian playwright and musician Jonathan Paiement (born 1985), Canadian ice hockey player Lucien Paiement (c. 1932 – 2013), Canadian physician and politician Mahée Paiement (born 1976), Canadian actress Pierre Paiement (born 1950), Canadian ice hockey player Rachel Paiement (born 1955), Canadian musician and songwriter Réal Paiement (born 1959), Canadian ice hockey player Rosaire Paiement (born 1945), Canadian ice hockey player Wilf Paiement (born 1955), Canadian ice hockey player