Pirjevec is a Slovene surname, found mostly in the Slovenian Littoral and among Slovenes in the Italian provinces of Trieste and Gorizia.

Notable persons with this surname include: Alenka Pirjevec (born 1945), Slovene puppeteer Avgust Pirjevec (1887–1943), Slovene literary historian Dušan Pirjevec (1921–1977), Slovene literary historian and philosopher Jože Pirjevec (born 1940), Slovene historian Marija Pirjevec, literary historian

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